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- Jason Waddell, P, Chicago Cubs
- Cory Wade, P, Los Angeles Dodgers
- Doug Waechter, P, Kansas City Royals
- Billy Wagner, P, New York Mets
- Mark Wagner, C, Boston Red Sox
- Ryan Wagner, P, Washington Nationals
- Adam Wainwright, P, St. Louis Cardinals
- Tim Wakefield, P, Boston Red Sox
- Jake Wald, SS, San Francisco Giants
- Jordan Walden, P, Anaheim Angels
- Chris Walker, CF, Philadelphia Phillies
- Jamie Walker, P, Baltimore Orioles
- Neil Walker, 3B, Pittsburgh Pirates
- Tyler Walker, P, Seattle Mariners
- Josh Wall, P, Los Angeles Dodgers
- Brett Wallace, 3B, St. Louis Cardinals
- Les Walrond, P, Philadelphia Phillies
- P.J. Walters, P, St. Louis Cardinals
- Chien-Ming Wang, P, New York Yankees
- Daryle Ward, 1B, Cincinnati Reds
- Brandon Waring, 3B, Cincinnati Reds
- Jarrod Washburn, P, Seattle Mariners
- Rico Washington, 3B, St. Louis Cardinals
- Ehren Wassermann, P, Chicago White Sox
- Chris Waters, P, Baltimore Orioles
- Anthony Watson, P, Pittsburgh Pirates
- Brandon Watson, LF, Arizona Diamondbacks
- Mike Watt, P, Los Angeles Dodgers
- Casey Weathers, P, Colorado Rockies
- David Weathers, P, Cincinnati Reds
- Jeff Weaver, P, Los Angeles Dodgers
- Jered Weaver, P, Anaheim Angels
- Brandon Webb, P, Arizona Diamondbacks
- Ryan Webb, P, Oakland Athletics
- Jon Weber, LF, Tampa Bay Rays
- Jemile Weeks, 2B, Oakland Athletics
- Rickie Weeks, 2B, Milwaukee Brewers
- Nicholas Weglarz, LF, Cleveland Indians
- Robert Weinhardt, P, Detroit Tigers
- Todd Wellemeyer, P, St. Louis Cardinals
- Casper Wells, RF, Detroit Tigers
- Jared Wells, P, Seattle Mariners
- Kip Wells, P, Kansas City Royals
- Randy Wells, P, Chicago Cubs
- Vernon Wells, CF, Toronto Blue Jays
- Jayson Werth, RF, Philadelphia Phillies
- Sean West, P, Florida Marlins
- Jake Westbrook, P, Cleveland Indians
- Dan Wheeler, P, Tampa Bay Rays
- Bill White, P, Texas Rangers
- Sean White, P, Seattle Mariners
- Josh Whitesell, 1B, Arizona Diamondbacks
- Eli Whiteside, C, San Francisco Giants
- Matthew Whitney, 1B, Washington Nationals
- Matt Wieters, C, Baltimore Orioles
- Ty Wigginton, 3B, Baltimore Orioles
- Matt Wilhite, P, Anaheim Angels
- Brad Wilkerson, RF, Boston Red Sox
- Colton Willems, P, Washington Nationals
- Jackson Williams, C, San Francisco Giants
- Jerome Williams, P, Oakland Athletics
- Randy Williams, P, Chicago White Sox
- Scott Williamson, P, Detroit Tigers
- Josh Willingham, LF, Washington Nationals
- Dontrelle Willis, P, Detroit Tigers
- Reggie Willits, LF, Anaheim Angels
- Bobby Wilson, C, Anaheim Angels
- Brian Wilson, P, San Francisco Giants
- C.J. Wilson, P, Texas Rangers
- Craig Wilson, 1B, Seattle Mariners
- Jack Wilson, SS, Pittsburgh Pirates
- Josh Wilson, SS, Arizona Diamondbacks
- Michael Wilson, RF, Seattle Mariners
- Corey Wimberly, 2B, Oakland Athletics
- David Winfree, RF, Minnesota Twins
- Randy Winn, RF, San Francisco Giants
- Flint Wipke, C, Anaheim Angels
- Dewayne Wise, CF, Chicago White Sox
- Matt Wise, P, New York Mets
- Chris Withrow, P, Los Angeles Dodgers
- Joseph Woerman, P, Seattle Mariners
- Randy Wolf, P, Los Angeles Dodgers
- Ross Wolf, P, Baltimore Orioles
- Brian Wolfe, P, Toronto Blue Jays
- Blake Wood, P, Kansas City Royals
- Brandon Wood, SS, Anaheim Angels
- Jason Wood, 1B, Florida Marlins
- Kerry Wood, P, Cleveland Indians
- Mike Wood, P, Florida Marlins
- Timothy Wood, P, Florida Marlins
- Travis Wood, P, Cincinnati Reds
- Jake Woods, P, Philadelphia Phillies
- Chris Woodward, SS, Seattle Mariners
- Mark Worrell, P, San Diego Padres
- Dan Worth, SS, Detroit Tigers
- Chase Wright, P, Milwaukee Brewers
- David Wright, 3B, New York Mets
- Jamey Wright, P, Kansas City Royals
- Matt Wright, P, Kansas City Royals
- Wesley Wright, P, Houston Astros
- Michael Wuertz, P, Oakland Athletics
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