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- Brandon Fahey, SS, Toronto Blue Jays
- Brian Falkenborg, P, San Diego Padres
- Kyle Farnsworth, P, Kansas City Royals
- Sal Fasano, C, Colorado Rockies
- Tim Fedroff, CF, Cleveland Indians
- Ryan Feierabend, P, Seattle Mariners
- Scott Feldman, P, Texas Rangers
- Pedro Feliciano, P, New York Mets
- Neftali Feliz, P, Texas Rangers
- Pedro Feliz, 3B, Philadelphia Phillies
- Miguel Fermin, C, Florida Marlins
- Prince Fielder, 1B, Milwaukee Brewers
- Josh Fields, 3B, Chicago White Sox
- Casey Fien, P, Detroit Tigers
- Alfredo Figaro, P, Detroit Tigers
- Chone Figgins, 3B, Anaheim Angels
- Luis Figueroa, SS, Anaheim Angels
- Nelson Figueroa, P, New York Mets
- Jeff Fiorentino, CF, Oakland Athletics
- Robert Fish, P, Anaheim Angels
- Carlos Fisher, P, Cincinnati Reds
- Ryan Flaherty, SS, Chicago Cubs
- David Flores, 3B, Houston Astros
- Jesus Flores, C, Washington Nationals
- Joshua Flores, CF, Houston Astros
- Randy Flores, P, Colorado Rockies
- Ron Flores, P, Cincinnati Reds
- Wilmer Flores, SS, New York Mets
- Tyler Flowers, C, Chicago White Sox
- Cliff Floyd, DH, San Diego Padres
- Gavin Floyd, P, Chicago White Sox
- Josh Fogg, P, Colorado Rockies
- Mike Fontenot, 2B, Chicago Cubs
- Shelby Ford, 2B, Pittsburgh Pirates
- Casey Fossum, P, New York Mets
- Keith Foulke, P, Oakland Athletics
- Dexter Fowler, CF, Colorado Rockies
- Chad Fox, P, Chicago Cubs
- Jake Fox, 1B, Chicago Cubs
- Jeff Francis, P, Colorado Rockies
- Ben Francisco, LF, Cleveland Indians
- Frank Francisco, P, Texas Rangers
- Juan Francisco, 3B, Cincinnati Reds
- Jeff Francoeur, RF, Atlanta Braves
- Kevin Frandsen, 2B, San Francisco Giants
- Ryan Franklin, P, St. Louis Cardinals
- Jason Frasor, P, Toronto Blue Jays
- Jeffrey Frazier, DH, Detroit Tigers
- Todd Frazier, SS, Cincinnati Reds
- Evan Frederickson, P, Milwaukee Brewers
- Ryan Freel, CF, Baltimore Orioles
- Frederick Freeman, 1B, Atlanta Braves
- David Freese, 3B, St. Louis Cardinals
- Chris Frey, CF, Colorado Rockies
- Evan Frey, CF, Arizona Diamondbacks
- Brian Friday, SS, Pittsburgh Pirates
- Christian Friedrich, P, Colorado Rockies
- Ernesto Frieri, P, San Diego Padres
- Neal Frontz, P, Tampa Bay Rays
- Emiliano Fruto, P, Atlanta Braves
- Eric Fryer, LF, Milwaukee Brewers
- Brian Fuentes, P, Anaheim Angels
- Kosuke Fukudome, RF, Chicago Cubs
- Kazuo Fukumori, P, Texas Rangers
- Jeff Fulchino, P, Houston Astros
- Sam Fuld, CF, Chicago Cubs
- Clayton Fuller, CF, Anaheim Angels
- Aaron Fultz, P, Cincinnati Reds
- Rafael Furcal, SS, Los Angeles Dodgers
- J.J. Furmaniak, SS, Philadelphia Phillies
- Brad Furnish, P, St. Louis Cardinals
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